National Water-Quality Assessment (NAWQA) Program
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By Bernard T. Nolan
[Journal of Environmental Quality, vol. 28, no. 5, Sep.-Oct. 1999, p. 1518-1527]Abstract
Principal components analysis (PCA) was performed with water-quality
data from studies conducted during 1993-1995 to explore potential
nitrate-attenuation processes in ground waters of the southeastern
United States. Nitrate reduction is an important attenuation process
in selected areas of the Southeast. A "nitrate-reduction" component
explains 23% of the total variance in the data and indicates that
nitrate and dissolved oxygen are inversely related to ammonium, iron,
manganese, and dissolved organic carbon. Additional components
extracted by PCA include "calcite dissolution" (18% of variance
explained) and "phosphate dissolution" (9% of variance explained).
Reducing conditions in ground waters of the region influence nitrate
behavior through bacterially mediated reduction in the presence of
organic matter, and by inhibition of nitrate formation in anoxic
ground water beneath forested areas. Component scores are consistent
with observed water-quality conditions in the region. For example,
median nitrate concentration in ground-water samples from the ALBE
Coastal Plain is <0.05 mg/L, median dissolved organic carbon
concentration is 4.2 mg/L, and median dissolved oxygen (DO)
concentration is 2.1 mg/L, consistent with denitrification. Nitrate
reduction does not occur uniformly throughout the Southeast. Median
DO concentrations in ground-water samples from the
Apalachicola-Chattahoochee-Flint River Basin are 6.2-7.1 mg/L, and
median nitrate concentrations are 0.61-2.2 mg/L, inconsistent with
denitrification. Similarly, median DO concentration in samples from
the Georgia-Florida Coastal Plain is 6.0 mg/L and median nitrate
concentration is 5.8 mg/L.
Table of Contents
Background
Methods
Results and discussion
Component loadings
Biologically mediated transformation of nitrate, iron, and manganese
Calcite dissolution
Phosphate dissolution
Component scores
Conclusions
Acknowledgments
References