Equipment & Supplies: Water-Quality Field instrumentation December 7, 1977 QUALITY OF WATER BRANCH TECHNICAL MEMORANDUM No. 78.02 Subject: Equipment & Supplies: Water-Quality Field instrumentation The Water Quality Advisory Committee has requested that the Quality of Water Branch periodically advise the Districts of water-quality field instruments that are recommended or considered reliable for field work. Quality of Water Branch Technical Memorandum No. 76.03 listed several instruments that were considered reliable at that time. In general, the instruments listed in that memo still are considered to be reliable, but in several cases newer models have been developed which represent improvements or refinements of the older models. On this basis, the following instruments are recommended by manufacturer only and not by model. Specific models will be recommended only when one model is known to be clearly superior to other models. Dissolved oxygen Yellow Springs Instruments Specific Conductance Electronic Switchgear, Beckman, Hydro Lab pH Meters Leeds & Northrup, Orion, Beckman pH Electrodes Orion, Corning, Sargent-Welch The above list does not imply that only instruments manufactured by these companies should be used in our field work, nor does it imply official endorsement by the Geological Survey. We realize that there probably are other instruments that can be used effectively in field operations. In fact most instruments currently available for the above measurements will meet Survey specifications for accuracy but insufficient data are available to judge their field use reliability. However, it should be kept in mind that the reliability of a measurement made with any instrument depends on proper calibration, operation, care, and maintenance. Without these, no instrument should be expected to produce proper results. The Quality of Water Branch, through the cooperation of many Districts, has been conducting a continuing but limited evaluation of selected field instruments. A past example is the evaluation of the NERA Hydrolab multiparameter recording unit (QW Branch Memo No. 75.16). Currently we are asking for evaluation information on the ISCO sampler (QW Branch Memo No. 77.09). Last March the Branch purchased four Graphics Controls combination pH gel electrodes (GC 51148). These were sent to four different field offices for experimental use, and the results of this limited test showed them to be unreliable. Recently we have purchased two multiparameter "Water Quality Checkers", Horiba model U-7. These will first be laboratory checked against the manufacturer's specifications and then sent to several Districts for reliability and performance evaluations. The recent replacement of the barrel filter unit with the plate filter and peristaltic pump unit has resulted in inquiries about the proper tubing to use in the heads of the peristaltic pumps. For water filtrationJ medical grade silicone tubing appears to offer relatively long pumping life plus #reedom from contamination with trace metals and other inorganics. However, silicone tubing has only a fair pressure rating and can "ballon" under difficult filtration operations. "Food grade" tygon tubing has better pressure capacity, but is stiffer and will cause the pump motor to work harder. This may cause the motor to overheat under some conditions. Teflon tubing is not recommended because it is too stiff, and the new Fluron F-5500R tubing should not be used because it may bleed contaminants after prolonged usage. Instrument manufactures have redesigned many pieces of equipment to feature digital readouts and to make the overall package smaller. One example is the new pocket-sized pH meter. The Alaska District has reported excellent success with a Digi-Sense meter and the Northeastern Region has recently acquired a similar type pH meter (X-Rite) for testing. The Branch would appreciate comments from other offices that had experience with similar units. The Branch will be reviewing equipment recommendations periodically as new equipment is developed and the Division's needs change. You are encouraged to relay your equipment experiences, observations, and needs, as well as your recommendations for equipment evaluations, to the Quality of Water Branch through your Regional Water-Quality Specialist. R. J. Pickering A, B, S, FO, PO