PUBLICATIONS - Report--"A study of the chemical quality of streamflow in Arkansas, " by Timothy Doak Steele December 7, 1971 QUALITY OF WATER BRANCH TECHNICAL MEMORANDUM NO. 72.05 Subject: PUBLICATIONS - Report--"A study of the chemical quality of streamflow in Arkansas, " by Timothy Doak Steele The design and operation of a water-resources information system requires that continuing reappraisal be made of that system through evaluation of the accumulated data. In recent years, the Water Resources Division has attempted to foster an orderly and scientific approach to the design and management of the water-quality information system represented by our Federal-State basic-data programs. One of the mechanisms used for this purpose has been the encouragement of pilot studies in water-quality data evaluation. The development of computer techniques in data handling has allowed us to begin some scattered qualitative and special- purpose studies centered on a suite of historical inorganic chemical constituents. The studies have been designed to test the usefulness of some of the available techniques for improving the design of district data-collection programs. The attached report, prepared in cooperation with the Arkansas District, is in fulfillment of the first phase of Project Ark-l9-F, one of several pilot data-evaluation studies authorized and partially funded by the Division. In the report are presented examples of several types of statistical analyses that can be made of streamflow chemical- quality data using routine computer programs. Application of the results of the analyses to synthesis and regionalization of data, and for assessing frequency-of-sampling alternatives, is described also. A key conclusion in Mr. Steele's study is that where a regression relationship exists for the dominantions and specific conductance, it is possible to estimate monthly mean concentrations and loads generally within 15-20 percent of the measured daily values. Through the use of a computer-oriented analytical approach such as that described in the report, the Division can improve the efficiency of its data programs and thereby free manpower and funds for expanding our data-collection efforts in the newly important aspects of water quality, such as organic compounds, minor elements, and biological studies. Techniques and computer programs are evolving beyond those used since the inception of this study. We should use these programs, along with proper scientific and mathematical techniques, to constantly improve both the quality and the adequacy of our data programs. It is hoped that the methods applied in the Arkansas study will be used increasingly by Division hydrologists to this end. Examples of similar pilot studies will follow. W.H. Durum Chief, Quality of Water Branch Attachment (in File Folder) WRD Distribution: A (Regional Hydrologists only), FO-LS