WATER-QUALITY DATA: Publication of Water Temperatures
March 13, 1975
QUALITY OF WATER BRANCH TECHNICAL MEMORANDUM NO. 75.15
Subject: WATER-QUALITY DATA: Publication of Water
Temperatures
The question of publication of negative water temperatures in
Geological Survey basic-data reports has recently been raised
by some WRD District personnel. This memorandum is to provide
guidance to Districts in deciding whether or not to publish
negative temperatures.
Review of pages D-143 through D-182 in the 49th edition of
CRC's Handbook of Chemistry and Physics provides a basis for
evaluation of freezing point depression associated with
increased concentrations of various chemical constituents. As
an example, concentrations of potassium chloride (KCl) and
sodium chloride (NaCl) are used to illustrate the freezing
point depression. Solute concentrations of 10,000 milligrams
anhydrous KCl or NaCl per 1,000 grams (approximately 1 litre)
solution will result in a depression of the freezing point by
0.46 or 0.59!C, respectively. The relation between solute
concentration and freezing point depression is linear to
concentrations of 30,000 milligrams/litre of KCl and NaCl.
Supercooled conditions can exist in streams characterized by
turbulent flow conditions, but generally this condition alone
will not result in temperatures colder than -0.1!C.
In summary, conditions may be found in which water
temperatures of less than 0!C are measured. Negative values
of water temperature in the range of 0!C to -1.0!C should be
published in Survey basic data reports after they have
received a thorough review and their accuracy verified. Any
values less than -1.0!C are highly questionable and should be
published only after a complete check of the calibration of
equipment used and discussion with the respective Regional
Water Quality Specialist.
R. J. Plckering
WRD Distribution: A, B, FO-L, PO