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WATER RESOURCES RESEARCH GRANT PROPOSAL
Project ID: 2003WA40B
Title: Non-point Pesticide Transport from Fields to Streams: Testing the Predictive Capability of a Geochemical Tracer Approach
Project Type: Research
Focus Categories: Non Point Pollution, Water Quality, Hydrogeochemistry
Keywords: Non point pollutants, lindane, triallate, pesticides, water quality, tracer
Start Date: 03/01/2003
End Date: 02/28/2004
Federal Funds: $25000.00
Matching Funds: $50971.00
Congressional District: Fifth
Principal Investigators: Allen-King, Richelle; Keller, C Kent (Dept Geology WSU)
Abstract: Lindane, an agricultural
insecticide that poses chronic risks to both human health and the environment,
is consistently found in surface waters within Washington State. Over the
past two years, our group has developed a geochemical tracer approach to
predict
agrochemical concentrations in surface waters that requires modest additional
data collection associated with existing gauging. Using the geochemical tracer
modeling approach, we can allocate pesticide discharges among and between
fields, and according to land use practice and drainage regime. This year,
the emergence of two new synthetic pesticides has caused a >80% decline
in lindane use in our watershed. Our goal is to use this basin-wide "experiment" to
test the geochemical tracer modeling approach as a means to quantify and
predict the consequences of changing management practices on total pesticide
stream discharge over multiple scales of study. The specific objectives of
the study are to:
1. Determine the time-constant (decay constant) that describes declining export
concentration associated with the cessation of lindane application at a field-to-basin
scale;
2. Test and refine the predictive capability of the geochemical model by comparing
forecasted behavior to observation;
3. Confirm a basin-wide decline in lindane mass discharge in response to diminished
application by comparing the lindane concentrations to those of another pesticide
with similar chemical attributes (and with unchanged application) over the
water year.
The completion of these objectives will lead to better understanding of the
processes that control agrochemical transport and improved means to plan management
strategies protective of water quality. Additionally, the improved understanding
of processes gained will be applicable to other pesticides that have chemical
properties similar to lindane.